BIODEGRADABILIDADE DE COMPÓSITOS REFORÇADOS POR FIBRAS DE BANANA E DE BATATA-DOCE
Palavras-chave:
Compósitos, fibras naturais, polímeros
Resumo
Diante do atual cenário de crescente desenvolvimento de novos produtos, o presente estudo analisou a durabilidade de compósitos reforçados com fibras de banana e de batata-doce, tendo o PVA como agente ligante, em formulações com híbridos e fibras únicas. No trabalho, foram conformadas três diferentes formulações, sendo as duas primeiras com fibras únicas de banana e de batata-doce e a última, hibridizando essas duas fibras. Nos ensaios de biodegradação em ambiente anaeróbio, o solo foi preparado segundo o procedimento G 160-03 da ASTM, com coletas periódicas de amostras ao longo de 12 semanas. As fibras foram caracterizadas quimicamente por via úmida (teores de lignina Klason e extrativos) e por microscopia ótica (presença de lignina residual). A biodegradabilidade dos compósitos foi avaliada por meio da perda de massa, colorimetria (método CIELAB), espectroscopia de infravermelho (FTIR), microscopia eletrônica de varredura (MEV) e espectroscopia de energia dispersiva (EDS). Nos resultados, os compósitos formulados com fibras de banana foram os que apresentaram maior resistência microbial e os compósitos híbridos apresentaram níveis intermediários de perda de massa e maior estabilidade colorimétrica.
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Referências
ALBINANTE, S.R.; PACHECO, E.B.A.V.;
VISCONTE, L.L.Y. Revisão dos tratamentos químicos
da fibra natural para mistura com poliolefinas.
Química Nova, v. 36, n. 1, p. 114-122, 2013.
Tomsen et al.
Revista Brasileira de Engenharia e Sustentabilidade, v.8, n,1, p 34-44, jul.2020.43
AMERICAN SOCIETY OF TESTING MATERIALS
ASTM. Standard practice for evaluating microbial
susceptibility on nonmetallic materials by
Laboratory soil burial. Philadelphia: ASTM. G 160
- 03, 2015.
ARANGUREN, M.I.; GONZÁLEZ, J.F.;
MOSIEWICKI, M.A. Biodegradation of a vegetable
oil based polyurethane and wood flour composites.
Polymer Testing, v. 31, n. 1, p. 7–15, 2012.
ARTHANARIESWARAN, V.P.; KUMARAVEL, A.;
KATHIRSELVAM, M. Evaluation of mechanical
properties of banana and sisal fiber reinforced epoxy
composites: Influence of glass fiber hybridization.
Materials & Design, v. 64, n. 12, p. 194–202, 2014.
CAVALCANTE, M.; FERREIRA, P.V.; PAIXÃO,
S.L.; COSTA, J.G.; PEREIRA, R.G.; MADALENA,
J.A.S. Potenciais produtivo e genético de clones de
batata-doce. Acta Scientiarum Agronomy, v. 31, n.
3, p. 421-426, 2009.
D’ALMEIDA, A.L.F.S.; CALADO, V.; BARRETO,
D.W. Acetilação da Fibra de Bucha (Luffa cylindrica).
Polímeros: Ciência e Tecnologia, v. 15, n. 1, p. 59-
62, 2005.
DAI, D.; FAN, M. Investigation of the dislocation
of natural fibres by Fourier-transform infrared
spectroscopy. Vibrational Spectroscopy, v. 55, n. 2,
p. 300–306, 2011.
DELUCIS, R.A.; CADEMARTORI, P.H.G.;
MISSIO, A.L.; GATTO, D.A. Decay resistance of
four fast-growing eucalypts wood exposed to three
types of fields. Maderas Ciencia y Tecnologia, v. 18,
n. 1, p. 33-42, 2016.
DELUCIS, R.A.; TABORDA, V.C.; CORREA, L.W.;
VEGA, R.A.; GATTO, D.A. Avaliação da cor dos
lenhos juvenil e adulto de cedro por meio do método
CIEL*a*b*. Tecnologia em Metalúrgica, Materiais e
Mineração, v. 11, n. 3, p. 251-259, 2014.
Food and Agriculture Organization of the United
States - FAOSTAT. 2020. Disponível em: http://www.
fao.org/faostat/en/#home
GADIOLI, R.; MORAIS, J.A.; WALDMAN W.R.;
DE PAOLI, M.A. The role of lignin in polypropylene
composites with semi-bleached cellulose fibers:
Mechanical properties and its activity as antioxidant.
Polymer Degradation and Stability, v. 108, n. 10, p.
23–34, 2014.
GEORGE, B.; SUTTIEB, E.; MERLIN, A.; DEGLISE,
X. Photodegradation and photostabilisation of wood
– the state of the art. Polymer Degradation and
Stability, v. 8, n. 2, p. 268-274, 2005.
HORINOUCHI, H.; KATSUYAMA, N.;
TAGUCHI, Y.; HYAKUMACHI, M. Control of
Fusarium crown and root rot of tomato in a soil
system by combination of a plant growth-promoting
fungus, Fusarium equiseti, and biodegradable pots.
Crop Protection, v. 27, n. 3–5, p. 859–864, 2008.
JEBRANE, M.; PICHAVANT, F.; SÈBE, G. A
comparative study on the acetylation of wood by
reaction with vinyl acetate and acetic anhydride.
Carbohydrate Polymers, v. 83, n. 2, p. 339-345,
2011.
JOSÉ, N.M.; PRADO, L.A.S.A. Materiais híbridos
orgânico-inorgânicos: preparação e algumas aplicações.
Química Nova, v. 28, n. 2, p. 281-288 2005.
KONICA MINOLTA. Precise color communication:
color control from perception to instrumentation.
Japan: Konica Minolta Sensing Inc. 2007.
KUMAR, M.; KHANNA, S. Shift in microbial
population in response to crystalline cellulose
degradation during enrichment with a semi-desert soil.
International Biodeterioration & Biodegradation,
v. 88, n. 3, p. 134–141, 2014.
LE DIGABEL, F.; BOQUILLON, F.; DOLE,
Tomsen et al.Revista Brasileira de Engenharia e Sustentabilidade, v.8, n,1, p 34-44, jul.2020.
P.; MONTIES, B.; AVEROUS, L. Properties of
Thermoplastic Composites Based on Wheat-Straw
Lignocellulosic Fillers. Journal of Applied Polymer
Science, v. 93, n. 1, p. 428–436, 2004.
LE TROËDEC, M.; PEYRATOUT, C.S.; SMITH,
A.; CHOTARD, T. Influence of various chemical
treatments on the interactions between hemp fibres
and a lime matrix. Journal of the European Ceramic
Society, v. 29, n. 10, p. 1861–1868, 2009.
LICHTEMBERG, L.A.; LICHTEMBERG, P.S.F.
Avanços na bananicultura brasileira. Revista Brasileira
de Fruticultura, v. 33, n. especial, p. 29-36, 2011.
MASEK, A.; ZABORSKI, M.; PIOTROWASKA, M.
Controlled degradation of biocomposites ENR/PCL
containing natural antioxidants. Comptes Rendus
Chimie, v. 17, n. 11, p. 1128–1135, 2014.
MATTOS, B.D.; CADEMARTORI, P.H.G.;
MAGALHÃES, W.E.; LAZAROTTO, M.; GATTO,
D.A. Thermal tools in the evaluation of decayed and
weathered wood polymer composites prepared by in
situ polymerization. Journal of Thermal Analysis
and Calorimetry, v. 121, n. 3, p. 1263-1271, 2015.
MOURA, A.; BOLBA, C.; DEMORI, R.; LIMA,
L.P.F.C.; SANATANA, R.M.C. Effect of rice husk
treatment with hot water on mechanical performance
in poly(hydroxybutyrate)/rice husk biocomposite.
Journal of Polymers and the Environment, v. 26, p.
2632-2639, 2018.
PANDEY, K.K. A note on the influence of extractives
on the photo-discoloration and photo-degradation of
wood. Polymer Degradation and Stability, v. 87, n.
2, p. 375–379, 2005.
SAGAR, N.A.; PAREEK, S.; SHARMA, S.; YAHIA,
E.M.; LOBO, M.G. Fruit and Vegetable Waste:
Bioactive Compounds, Their Extraction, and Possible
Utilization. Comprehensive Reviews in Food Science
and Food Safety, v. 17, n. 3, 512-531, 2018.
SAPUAN, S.M.; LEENIE, A.; HARIMI, M.; BENG,
Y.K. Mechanical properties of woven banana fibre
reinforced epoxy composites. Materials and Design,
v. 27, n. 8, p. 689–693, 2006.
SANTOS P.S.B.; CADEMARTORI, P.H.G.;
PRADO, R.; GATTO, D.A.; LABIDI, J. Composition
and structure of organosolv lignins from four eucalypt
species. Wood Science and Technology, v, 48, n. 4, p.
873–885, 2014.
SILVA, A.M.B.; LUZ, S.M.; SIVA, I.; JAPPES,
J.T.W.; AMICO, S.C. Effect of silane treatment on the
curaua fibre/polyester interface. Plastics, Rubber and
Composites, v. 48, n. 4, p. 160-167, 2019.
TAPPI - T204, 1997. Solvent Extractives of Wood and
Pulp 2000–2001 TAPPI Test Methods.
TAPPI - T222, 1998. Acid-insoluble Lignin in Wood
and Pulp 2000–2001 TAPPI Test Methods.
TELMO, C.; LOUSADA, J. The explained variation
by lignin and extractive contents on higher heating
value of wood. Biomass and Bioenergy, v. 35, n. 5, p.
1663–1667, 2011.
TOMSIC, B.; ILEC, E.; ZERJAV, M.; HLADNIK, A.
SIMONCIC, A.; SIMONCIC, B. Characterisation
and functional properties of antimicrobialbio-barriers
formed by natural fibres. Colloids and Surfaces B:
Biointerfaces, v. 122, n. 10, p. 72-78, 2014.
ZIMMERMANN, M.V.; TURELLA, T.C.;
ZATTERA, A.J.; SANTANA, R.M. Influência
do tratamento químico da fibra de bananeira em
compósitos de poli (etileno-co-acetato de vinila) com
e sem agente de expansão. Polímeros, v. 24, n. 1, p.
58-64, 2014.
VISCONTE, L.L.Y. Revisão dos tratamentos químicos
da fibra natural para mistura com poliolefinas.
Química Nova, v. 36, n. 1, p. 114-122, 2013.
Tomsen et al.
Revista Brasileira de Engenharia e Sustentabilidade, v.8, n,1, p 34-44, jul.2020.43
AMERICAN SOCIETY OF TESTING MATERIALS
ASTM. Standard practice for evaluating microbial
susceptibility on nonmetallic materials by
Laboratory soil burial. Philadelphia: ASTM. G 160
- 03, 2015.
ARANGUREN, M.I.; GONZÁLEZ, J.F.;
MOSIEWICKI, M.A. Biodegradation of a vegetable
oil based polyurethane and wood flour composites.
Polymer Testing, v. 31, n. 1, p. 7–15, 2012.
ARTHANARIESWARAN, V.P.; KUMARAVEL, A.;
KATHIRSELVAM, M. Evaluation of mechanical
properties of banana and sisal fiber reinforced epoxy
composites: Influence of glass fiber hybridization.
Materials & Design, v. 64, n. 12, p. 194–202, 2014.
CAVALCANTE, M.; FERREIRA, P.V.; PAIXÃO,
S.L.; COSTA, J.G.; PEREIRA, R.G.; MADALENA,
J.A.S. Potenciais produtivo e genético de clones de
batata-doce. Acta Scientiarum Agronomy, v. 31, n.
3, p. 421-426, 2009.
D’ALMEIDA, A.L.F.S.; CALADO, V.; BARRETO,
D.W. Acetilação da Fibra de Bucha (Luffa cylindrica).
Polímeros: Ciência e Tecnologia, v. 15, n. 1, p. 59-
62, 2005.
DAI, D.; FAN, M. Investigation of the dislocation
of natural fibres by Fourier-transform infrared
spectroscopy. Vibrational Spectroscopy, v. 55, n. 2,
p. 300–306, 2011.
DELUCIS, R.A.; CADEMARTORI, P.H.G.;
MISSIO, A.L.; GATTO, D.A. Decay resistance of
four fast-growing eucalypts wood exposed to three
types of fields. Maderas Ciencia y Tecnologia, v. 18,
n. 1, p. 33-42, 2016.
DELUCIS, R.A.; TABORDA, V.C.; CORREA, L.W.;
VEGA, R.A.; GATTO, D.A. Avaliação da cor dos
lenhos juvenil e adulto de cedro por meio do método
CIEL*a*b*. Tecnologia em Metalúrgica, Materiais e
Mineração, v. 11, n. 3, p. 251-259, 2014.
Food and Agriculture Organization of the United
States - FAOSTAT. 2020. Disponível em: http://www.
fao.org/faostat/en/#home
GADIOLI, R.; MORAIS, J.A.; WALDMAN W.R.;
DE PAOLI, M.A. The role of lignin in polypropylene
composites with semi-bleached cellulose fibers:
Mechanical properties and its activity as antioxidant.
Polymer Degradation and Stability, v. 108, n. 10, p.
23–34, 2014.
GEORGE, B.; SUTTIEB, E.; MERLIN, A.; DEGLISE,
X. Photodegradation and photostabilisation of wood
– the state of the art. Polymer Degradation and
Stability, v. 8, n. 2, p. 268-274, 2005.
HORINOUCHI, H.; KATSUYAMA, N.;
TAGUCHI, Y.; HYAKUMACHI, M. Control of
Fusarium crown and root rot of tomato in a soil
system by combination of a plant growth-promoting
fungus, Fusarium equiseti, and biodegradable pots.
Crop Protection, v. 27, n. 3–5, p. 859–864, 2008.
JEBRANE, M.; PICHAVANT, F.; SÈBE, G. A
comparative study on the acetylation of wood by
reaction with vinyl acetate and acetic anhydride.
Carbohydrate Polymers, v. 83, n. 2, p. 339-345,
2011.
JOSÉ, N.M.; PRADO, L.A.S.A. Materiais híbridos
orgânico-inorgânicos: preparação e algumas aplicações.
Química Nova, v. 28, n. 2, p. 281-288 2005.
KONICA MINOLTA. Precise color communication:
color control from perception to instrumentation.
Japan: Konica Minolta Sensing Inc. 2007.
KUMAR, M.; KHANNA, S. Shift in microbial
population in response to crystalline cellulose
degradation during enrichment with a semi-desert soil.
International Biodeterioration & Biodegradation,
v. 88, n. 3, p. 134–141, 2014.
LE DIGABEL, F.; BOQUILLON, F.; DOLE,
Tomsen et al.Revista Brasileira de Engenharia e Sustentabilidade, v.8, n,1, p 34-44, jul.2020.
P.; MONTIES, B.; AVEROUS, L. Properties of
Thermoplastic Composites Based on Wheat-Straw
Lignocellulosic Fillers. Journal of Applied Polymer
Science, v. 93, n. 1, p. 428–436, 2004.
LE TROËDEC, M.; PEYRATOUT, C.S.; SMITH,
A.; CHOTARD, T. Influence of various chemical
treatments on the interactions between hemp fibres
and a lime matrix. Journal of the European Ceramic
Society, v. 29, n. 10, p. 1861–1868, 2009.
LICHTEMBERG, L.A.; LICHTEMBERG, P.S.F.
Avanços na bananicultura brasileira. Revista Brasileira
de Fruticultura, v. 33, n. especial, p. 29-36, 2011.
MASEK, A.; ZABORSKI, M.; PIOTROWASKA, M.
Controlled degradation of biocomposites ENR/PCL
containing natural antioxidants. Comptes Rendus
Chimie, v. 17, n. 11, p. 1128–1135, 2014.
MATTOS, B.D.; CADEMARTORI, P.H.G.;
MAGALHÃES, W.E.; LAZAROTTO, M.; GATTO,
D.A. Thermal tools in the evaluation of decayed and
weathered wood polymer composites prepared by in
situ polymerization. Journal of Thermal Analysis
and Calorimetry, v. 121, n. 3, p. 1263-1271, 2015.
MOURA, A.; BOLBA, C.; DEMORI, R.; LIMA,
L.P.F.C.; SANATANA, R.M.C. Effect of rice husk
treatment with hot water on mechanical performance
in poly(hydroxybutyrate)/rice husk biocomposite.
Journal of Polymers and the Environment, v. 26, p.
2632-2639, 2018.
PANDEY, K.K. A note on the influence of extractives
on the photo-discoloration and photo-degradation of
wood. Polymer Degradation and Stability, v. 87, n.
2, p. 375–379, 2005.
SAGAR, N.A.; PAREEK, S.; SHARMA, S.; YAHIA,
E.M.; LOBO, M.G. Fruit and Vegetable Waste:
Bioactive Compounds, Their Extraction, and Possible
Utilization. Comprehensive Reviews in Food Science
and Food Safety, v. 17, n. 3, 512-531, 2018.
SAPUAN, S.M.; LEENIE, A.; HARIMI, M.; BENG,
Y.K. Mechanical properties of woven banana fibre
reinforced epoxy composites. Materials and Design,
v. 27, n. 8, p. 689–693, 2006.
SANTOS P.S.B.; CADEMARTORI, P.H.G.;
PRADO, R.; GATTO, D.A.; LABIDI, J. Composition
and structure of organosolv lignins from four eucalypt
species. Wood Science and Technology, v, 48, n. 4, p.
873–885, 2014.
SILVA, A.M.B.; LUZ, S.M.; SIVA, I.; JAPPES,
J.T.W.; AMICO, S.C. Effect of silane treatment on the
curaua fibre/polyester interface. Plastics, Rubber and
Composites, v. 48, n. 4, p. 160-167, 2019.
TAPPI - T204, 1997. Solvent Extractives of Wood and
Pulp 2000–2001 TAPPI Test Methods.
TAPPI - T222, 1998. Acid-insoluble Lignin in Wood
and Pulp 2000–2001 TAPPI Test Methods.
TELMO, C.; LOUSADA, J. The explained variation
by lignin and extractive contents on higher heating
value of wood. Biomass and Bioenergy, v. 35, n. 5, p.
1663–1667, 2011.
TOMSIC, B.; ILEC, E.; ZERJAV, M.; HLADNIK, A.
SIMONCIC, A.; SIMONCIC, B. Characterisation
and functional properties of antimicrobialbio-barriers
formed by natural fibres. Colloids and Surfaces B:
Biointerfaces, v. 122, n. 10, p. 72-78, 2014.
ZIMMERMANN, M.V.; TURELLA, T.C.;
ZATTERA, A.J.; SANTANA, R.M. Influência
do tratamento químico da fibra de bananeira em
compósitos de poli (etileno-co-acetato de vinila) com
e sem agente de expansão. Polímeros, v. 24, n. 1, p.
58-64, 2014.
Publicado
2021-11-23
Como Citar
Tomsen, F., de Avila Delucis, R., C.T. Veiga, F., A. Gatto, D., & R. F. Gonçalves, M. (2021). BIODEGRADABILIDADE DE COMPÓSITOS REFORÇADOS POR FIBRAS DE BANANA E DE BATATA-DOCE. Revista Brasileira De Engenharia E Sustentabilidade, 8(1), 34-44. Recuperado de https://revistas.ufpel.edu.br/index.php/rbes/article/view/237
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Seção
ENGENHARIA DE MATERIAIS
