FOTOLUMINESCÊNCIA DA ZIRCÔNIA ESTABILIZADA COM ÍTRIO RECOBERTA COM CERIA
ESTUDO DA INFLUÊNCIA DO REVESTIMENTO
Palavras-chave:
zircônia estabilizada com ítrio, céria, interface, recobrimento, fotoluminescência
Resumo
Na síntese dos nanocompósitos preparou-se, utilizando o método Pechini, o citrato de céria para recobrir o ZrO2 estabilizado com Ítrio comercial nas proporções de 1, 3 e 5% em mol de CeO2. Foram utilizados na caracterização dos nanocompósitos de ZrO2 estabilizado com Ítrio recoberto com ceria as técnicas de Difração de Raios X, Microscopia Eletrônica de Varredura, Energia Dispersiva de Raios X e Emissão Fotoluminescente, a propriedade de FL foi avaliada a temperatura ambiente. Observando que, quando variando a porcentagem da quantidade de mol no recobrimento há uma influência na intensidade FL do material, indicando que uma menor porcentagem em mol de recobrimento provoca uma maior emissão quando comparado ao material com maior porcentagem em mol de recobrimento, devido a geração de um grau de ordem e desordem proveniente da interface entre os dois materiais.
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Referências
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ARAÚJO, V. D.; AVANSI, W.; CARVALHO, H. B.; MOREIRA,
M. L.; LONGO, E.; RIBEIRO, C.; BERNARDI, M. I. B. et
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CrystEngComm, v.14, p.1150-1154, 2012.
ASLAM M.; QAMAR M. T.; SOOMRO M. T.; IQBAL M.
I.; SALAH N.; ALMEELBI T.; GONDAL M. A. Te efect of
sunlight induced surface defects on the photocatalytic activity of
nanosized CeO2 for the degradation of phenol and its derivatives
Appl. Catal., B: Environ., v.180, p. 391, 2016.
BARANCHIKOV A. E.; POLEZHAEVA O. S.; IVANOV V.
K.; TRETYAKOV Y. D. Lattice expansion and oxygen nonstoichiometry of nanocrystalline ceria CrystEngComm., v.12, p.
3531, 2010.
16
Figura 3. Imagens de MEV: A. 1% mol CeO2 B. 3% mol CeO2
C. 5% mol CeO2
D. EDS da ZrO2
estabilidada com
Ítrio recoberta com CeO2
.
Rodrigues et al.
Revista Brasileira de Engenharia e Sustentabilidade, v.5, especial, p.13-17, dez. 2018
CHANG C. J.; LINC. Y.; HSU M. H. Enhanced photocatalytic
activity of Ce-doped ZnO nanorods under UV and visible light J.
Taiwan Inst. Chem. Eng., v.45, p.1954-1963, 2014.
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HOSSEINI H. A.; GHOLAMI L. Green synthesis and evaluation
of metabolic activity of starch mediated nanoceria Ceram. Int.,
v.40, p. 2041, 2014.
DJURICIC B.; PICKERING S. Nanostructured Cerium Oxide:
Preparation and Properties of Weakly-agglomerated Powders.
Journal of European Ceramic Society v.19, p.1999, 1925
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RAUBACH C. W.; CARREÑO N. L.V.; PROBST L. F. D.;
LONGO E.; FAJARDO H. V. Gadolinium-doped cerium oxide
nanorods: novel active catalysts for ethanol reforming. Journal of
Materials Science, v. 45, p. 593-598, 2010.
GODINHO M.J.; GONCALVES R. F.; SANTOS L. P. S.;
VARELA, J.A.; LONGO E.; LEITE E. R. Room temperature
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2007.
GODINHO M.J.; RIBEIRO C.; LONGO E.; LEITE E. R.
Infuence of Microwave Heating on the Growth of GadoliniumDoped Cerium Oxide Nanorods. Crystal Growth & Design, v.
8, p. 384-386, 2008.
GONÇALVES R. F.; CASTRO D. A.; SANTOS M. R. C.;
FIGUEIREDO A. T. ; BARRADO C. M.; LEITE E. R.;
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dopada com gadolínio por sistema de aquecimento por microondas. Cerâmica (São Paulo. Impresso), v. 59, p. 426-430,
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properties at the grain boundary of barium zirconate based proton
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IMASHUKU, S. et al. Efect of isovalentcation substitution
on conductivity and microstructure of sintered yttrium-doped
barium zirconate Journal of Alloys and Compounds. v.490,
p.672–676, 2010.
JI, S. et al. Performance enhancement of thin-flm ceramic
electrolyte fuel cell using bi-layered yttrium-doped barium
zirconate. Tin Solid Films. v.539, p.117–121, 2013.
KASICA, K.G. et al. Optimization of microstructure and
properties of acceptor-doped barium cerate. Solid State Ionics.
v.225, p.245–249, 2012.
LE, S. et al. Sintering and electrochemical performance of Y2O3-
doped barium zirconate with Bi2O3 as sintering aids. Journal of
Power Sources. v.232, p.219-223, 2013.
LI, J. et al. Chemical stability of Y-doped Ba(Ce,Zr)O3 perovskites
in H2S-containing H2 ElectrochimicaActa. v.53, p.3701–3707,
2008.
LIU, M. et al. Rational SOFC material design: new advances and
tools. Materials today. v.14, p.11, 2011.
MUCCILLO, R.; MUCCILLO, E.N.S.; KLEITZ, M.
Densifcation and enhancement of the grain boundary
conductivity of gadolinium-doped barium cerate by ultra fast
fash grain welding. Journal of the European Ceramic Society.
v.32, p.2311–2316, 2012.
PARK, J.S. et al. Efects of ZnO addition methods on proton
conductivities of barium zirconate modifed by ytterbium. Solid
State Ionics. v.224, p.1–5, 2012.
PLAZA, R.C.; QUIRANTES, A.; DELGADO, A.V., Stability
of dispersions of colloidal hematite/Yttrium oxide core-shell
particles. J. Colloid Interface Sci., v.252, p.102, 2002.
SOUZA, E.C.C; MUCCILLO, R. Properties and Applications
of Perovskite Proton Conductors. Materials Research. v.13,
p.385-394, 2010.
WANG, S; et al. Two-step sintering of ultrafne-grained barium
cerate próton conducting ceramics. Electrochimica Acta. v.87,
p.194– 200, 2013.
YIN, J.; QIAN, X.; YIN, J.; SHI, M.; ZHANG, J.; ZHOU, G.,
Preparation of polystyrene/zirconia core-shell microspheres and
zirconia hollow shells. Inorg. Chem. Commun., v.6, p.942,
2003.
nanostructured zirconium oxide synthesized by hydrothermal
process Journal of Nanoparticles Research v.12, p.3105–3110,
2010.
ARAÚJO, V. D.; AVANSI, W.; CARVALHO, H. B.; MOREIRA,
M. L.; LONGO, E.; RIBEIRO, C.; BERNARDI, M. I. B. et
al. CeO2 nanoparticles syntesized by a microwave-assisted
hydrothermal method: evolution from nanospheres to nanorods.
CrystEngComm, v.14, p.1150-1154, 2012.
ASLAM M.; QAMAR M. T.; SOOMRO M. T.; IQBAL M.
I.; SALAH N.; ALMEELBI T.; GONDAL M. A. Te efect of
sunlight induced surface defects on the photocatalytic activity of
nanosized CeO2 for the degradation of phenol and its derivatives
Appl. Catal., B: Environ., v.180, p. 391, 2016.
BARANCHIKOV A. E.; POLEZHAEVA O. S.; IVANOV V.
K.; TRETYAKOV Y. D. Lattice expansion and oxygen nonstoichiometry of nanocrystalline ceria CrystEngComm., v.12, p.
3531, 2010.
16
Figura 3. Imagens de MEV: A. 1% mol CeO2 B. 3% mol CeO2
C. 5% mol CeO2
D. EDS da ZrO2
estabilidada com
Ítrio recoberta com CeO2
.
Rodrigues et al.
Revista Brasileira de Engenharia e Sustentabilidade, v.5, especial, p.13-17, dez. 2018
CHANG C. J.; LINC. Y.; HSU M. H. Enhanced photocatalytic
activity of Ce-doped ZnO nanorods under UV and visible light J.
Taiwan Inst. Chem. Eng., v.45, p.1954-1963, 2014.
DARROUDI M.; SARANI M.; OSKUEE R. K.; ZAK A. K.;
HOSSEINI H. A.; GHOLAMI L. Green synthesis and evaluation
of metabolic activity of starch mediated nanoceria Ceram. Int.,
v.40, p. 2041, 2014.
DJURICIC B.; PICKERING S. Nanostructured Cerium Oxide:
Preparation and Properties of Weakly-agglomerated Powders.
Journal of European Ceramic Society v.19, p.1999, 1925
GODINHO M. J.; GONCALVES R. F.; LEITE E. R.;
RAUBACH C. W.; CARREÑO N. L.V.; PROBST L. F. D.;
LONGO E.; FAJARDO H. V. Gadolinium-doped cerium oxide
nanorods: novel active catalysts for ethanol reforming. Journal of
Materials Science, v. 45, p. 593-598, 2010.
GODINHO M.J.; GONCALVES R. F.; SANTOS L. P. S.;
VARELA, J.A.; LONGO E.; LEITE E. R. Room temperature
co-precipitation of nanocrystalline CeO2 and Ce0.8 Gd0.2 O1.9
δ powder. Materials Letters (General ed.), v. 61, p. 1904-1907,
2007.
GODINHO M.J.; RIBEIRO C.; LONGO E.; LEITE E. R.
Infuence of Microwave Heating on the Growth of GadoliniumDoped Cerium Oxide Nanorods. Crystal Growth & Design, v.
8, p. 384-386, 2008.
GONÇALVES R. F.; CASTRO D. A.; SANTOS M. R. C.;
FIGUEIREDO A. T. ; BARRADO C. M.; LEITE E. R.;
GODINHO M.J. Estudo do crescimento de nanoftas de céria
dopada com gadolínio por sistema de aquecimento por microondas. Cerâmica (São Paulo. Impresso), v. 59, p. 426-430,
2013.
IGUCHI, F.; SATA, N.; YUGAMI, H. Proton transport
properties at the grain boundary of barium zirconate based proton
conductors for intermediate temperature operating SOFC.
Journal of Materials Chemistry v.20, p.6265–6270, 2010.
IMASHUKU, S. et al. Efect of isovalentcation substitution
on conductivity and microstructure of sintered yttrium-doped
barium zirconate Journal of Alloys and Compounds. v.490,
p.672–676, 2010.
JI, S. et al. Performance enhancement of thin-flm ceramic
electrolyte fuel cell using bi-layered yttrium-doped barium
zirconate. Tin Solid Films. v.539, p.117–121, 2013.
KASICA, K.G. et al. Optimization of microstructure and
properties of acceptor-doped barium cerate. Solid State Ionics.
v.225, p.245–249, 2012.
LE, S. et al. Sintering and electrochemical performance of Y2O3-
doped barium zirconate with Bi2O3 as sintering aids. Journal of
Power Sources. v.232, p.219-223, 2013.
LI, J. et al. Chemical stability of Y-doped Ba(Ce,Zr)O3 perovskites
in H2S-containing H2 ElectrochimicaActa. v.53, p.3701–3707,
2008.
LIU, M. et al. Rational SOFC material design: new advances and
tools. Materials today. v.14, p.11, 2011.
MUCCILLO, R.; MUCCILLO, E.N.S.; KLEITZ, M.
Densifcation and enhancement of the grain boundary
conductivity of gadolinium-doped barium cerate by ultra fast
fash grain welding. Journal of the European Ceramic Society.
v.32, p.2311–2316, 2012.
PARK, J.S. et al. Efects of ZnO addition methods on proton
conductivities of barium zirconate modifed by ytterbium. Solid
State Ionics. v.224, p.1–5, 2012.
PLAZA, R.C.; QUIRANTES, A.; DELGADO, A.V., Stability
of dispersions of colloidal hematite/Yttrium oxide core-shell
particles. J. Colloid Interface Sci., v.252, p.102, 2002.
SOUZA, E.C.C; MUCCILLO, R. Properties and Applications
of Perovskite Proton Conductors. Materials Research. v.13,
p.385-394, 2010.
WANG, S; et al. Two-step sintering of ultrafne-grained barium
cerate próton conducting ceramics. Electrochimica Acta. v.87,
p.194– 200, 2013.
YIN, J.; QIAN, X.; YIN, J.; SHI, M.; ZHANG, J.; ZHOU, G.,
Preparation of polystyrene/zirconia core-shell microspheres and
zirconia hollow shells. Inorg. Chem. Commun., v.6, p.942,
2003.
Publicado
2021-11-30
Como Citar
de Matos Rodrigues, M. H., de Oliveira Figueiredo, J. T., Mesquita Borges, K. C., Gonçalves, R. de F., Siu Li, M., do Carmo Gurgel, M. F., Lenin Villarreal Carreño, N., de Azevedo Marques, A. P., Villela Motta, F., & Godinho Junior, M. (2021). FOTOLUMINESCÊNCIA DA ZIRCÔNIA ESTABILIZADA COM ÍTRIO RECOBERTA COM CERIA: ESTUDO DA INFLUÊNCIA DO REVESTIMENTO. Revista Brasileira De Engenharia E Sustentabilidade, 5(3), 13-17. Recuperado de https://revistas.ufpel.edu.br/index.php/rbes/article/view/276
